Self-assembly of a Si-based cage by the formation of 24 equivalent covalent bonds

Jessica L. Holmes; Brendan F. Abrahams; Anna Ahveninen; Berin A. Boughton; Timothy A. Hudson; Richard Robson; Dinaiz Thinagaran

doi:10.1039/C8CC06405A

Self-assembly of a Si-based cage by the formation of 24 equivalent covalent bonds

Jessica L. Holmes
, Brendan F. Abrahams
, Anna Ahveninen
, Berin A. Boughton
, Timothy A. Hudson
, Richard Robson
, Dinaiz Thinagaran

Australian Council for Educational Research (ACER)

Research output: Contribution to journal › Article › peer-review

Original language	English
Journal	Chemical Communications
Volume	54
Issue number	84
DOIs	https://doi.org/10.1039/C8CC06405A
Publication status	Published - 1 Jan 2018

Disciplines

Organic Chemistry
Inorganic Chemistry

Access to Document

10.1039/C8CC06405ALicence: Unspecified

https://pubs.rsc.org/en/Content/ArticleLanding/2018/CC/C8CC06405A#!

Cite this

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title = "Self-assembly of a Si-based cage by the formation of 24 equivalent covalent bonds",

author = "Holmes, \{Jessica L.\} and Abrahams, \{Brendan F.\} and Anna Ahveninen and Boughton, \{Berin A.\} and Hudson, \{Timothy A.\} and Richard Robson and Dinaiz Thinagaran",

note = "A robust, nano-sized covalent cage, of composition, [(PhSi)6(ctc)4]6− (H6ctc = cyclotricatechylene) has been prepared in a simple reaction in good yield. The tetrahedral anionic cage is stable in both the solid and solution state and exhibits an affinity for Cs+ ions which bind to the internal surface of the",

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T1 - Self-assembly of a Si-based cage by the formation of 24 equivalent covalent bonds

AU - Holmes, Jessica L.

AU - Abrahams, Brendan F.

AU - Ahveninen, Anna

AU - Boughton, Berin A.

AU - Hudson, Timothy A.

AU - Robson, Richard

AU - Thinagaran, Dinaiz

N1 - A robust, nano-sized covalent cage, of composition, [(PhSi)6(ctc)4]6− (H6ctc = cyclotricatechylene) has been prepared in a simple reaction in good yield. The tetrahedral anionic cage is stable in both the solid and solution state and exhibits an affinity for Cs+ ions which bind to the internal surface of the

PY - 2018/1/1

Y1 - 2018/1/1

U2 - 10.1039/C8CC06405A

DO - 10.1039/C8CC06405A

M3 - Article

VL - 54

JO - Chemical Communications

JF - Chemical Communications

IS - 84

ER -